Paper Abstract and Keywords |
Presentation |
2014-12-19 15:30
Electrochemical ammonia oxidation by carbon supported multilayered shell-core noble metal particle catalysts Ryo Shirasaka, Eiji Kudo, Hidenobu Shiroishi (TNCT), Morihiro Saito (TUAT), Hiraku Ota, Mikka N.- Gamo (TU) OME2014-73 Link to ES Tech. Rep. Archives: OME2014-73 |
Abstract |
(in Japanese) |
(See Japanese page) |
(in English) |
Ammonia is expected for the energy source of next generation, because the domestic production is almost 1.2 million ton a year. A highly active ammonia oxidation (AO) catalysts at low temperatures needs to be developed to use ammonia as a fuel for the direct ammonia fuel cells (DAmFCs). In this study, shell-core catalysts made from the Pt, Rh and Ir complexes were synthesized with the combination of microwave-polyol, ethanol reductive and improved Cu-UPD (underpotential deposition) methods, and the performance of AO was evaluated. The results showed that the catalytic activity of the Pt shell-Ir core with the thinnest shell for AO was the highest in the catalysts. And the catalytic activity for AO with Pt outer shell/ Ir inner shell/ Rh core catalysts was lower than that with the thinnest Pt shell / Ir core catalyst, suggesting that an electronic effect from Rh core reached to the Pt outer shell. |
Keyword |
(in Japanese) |
(See Japanese page) |
(in English) |
shell-core metal catalysts / multilayered / shell thickness / ammonia oxidation / / / / |
Reference Info. |
IEICE Tech. Rep., vol. 114, no. 383, OME2014-73, pp. 41-44, Dec. 2014. |
Paper # |
OME2014-73 |
Date of Issue |
2014-12-12 (OME) |
ISSN |
Print edition: ISSN 0913-5685 Online edition: ISSN 2432-6380 |
Copyright and reproduction |
All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034) |
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OME2014-73 Link to ES Tech. Rep. Archives: OME2014-73 |
Conference Information |
Committee |
OME |
Conference Date |
2014-12-19 - 2014-12-19 |
Place (in Japanese) |
(See Japanese page) |
Place (in English) |
Kikai-Shinko-Kaikan Bldg |
Topics (in Japanese) |
(See Japanese page) |
Topics (in English) |
battery, electrochemistry, surface modification, catalyst, in situ obsrvation, capacito |
Paper Information |
Registration To |
OME |
Conference Code |
2014-12-OME |
Language |
Japanese |
Title (in Japanese) |
(See Japanese page) |
Sub Title (in Japanese) |
(See Japanese page) |
Title (in English) |
Electrochemical ammonia oxidation by carbon supported multilayered shell-core noble metal particle catalysts |
Sub Title (in English) |
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Keyword(1) |
shell-core metal catalysts |
Keyword(2) |
multilayered |
Keyword(3) |
shell thickness |
Keyword(4) |
ammonia oxidation |
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1st Author's Name |
Ryo Shirasaka |
1st Author's Affiliation |
Tokyo National College of Technology (TNCT) |
2nd Author's Name |
Eiji Kudo |
2nd Author's Affiliation |
Tokyo National College of Technology (TNCT) |
3rd Author's Name |
Hidenobu Shiroishi |
3rd Author's Affiliation |
Tokyo National College of Technology (TNCT) |
4th Author's Name |
Morihiro Saito |
4th Author's Affiliation |
Tokyo University of Agriculture and Technology (TUAT) |
5th Author's Name |
Hiraku Ota |
5th Author's Affiliation |
Toyo University (TU) |
6th Author's Name |
Mikka N.- Gamo |
6th Author's Affiliation |
Toyo University (TU) |
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Speaker |
Author-1 |
Date Time |
2014-12-19 15:30:00 |
Presentation Time |
15 minutes |
Registration for |
OME |
Paper # |
OME2014-73 |
Volume (vol) |
vol.114 |
Number (no) |
no.383 |
Page |
pp.41-44 |
#Pages |
4 |
Date of Issue |
2014-12-12 (OME) |
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