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Paper Abstract and Keywords
Presentation 2012-02-10 15:35
Effect of Zinc Surface Modification on Electrochemical Properties for Alkaline Zn-based Secondary Battery
Tomokazu Yamane, Akiyoshi Nakata, Toshiro Hirai, Zempachi Ogumi (Kyoto Univ.) EE2011-58 CPM2011-174 Link to ES Tech. Rep. Archives: CPM2011-174
Abstract (in Japanese) (See Japanese page) 
(in English) The commercialization of zinc/air secondary battery is limited because of its low cycling life. Shape change and dendrite growth in zinc anode have been reported to degrade cycling performance. Such phenomena are mainly caused by the high solubility of zincate in alkaline electrolyte. We have tried to coat zinc anode with a cation exchange polymer to suppress the solubility of zincate and estimated its effect on the cell cycling performance.
Galvanostatic polarization, XRD, SEM and EIS showed that the surface modified electrode suppressed the elution of zincate into the alkaline electrolyte. In addition, cell cycling tests showed the surface modified zinc electrode improved cycling performance.
Keyword (in Japanese) (See Japanese page) 
(in English) zinc/air secondary battery / anode / cation exchage polymer / cycle life / shape change / / /  
Reference Info. IEICE Tech. Rep., vol. 111, no. 434, CPM2011-174, pp. 33-37, Feb. 2012.
Paper # CPM2011-174 
Date of Issue 2012-02-03 (EE, CPM) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
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All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
Download PDF EE2011-58 CPM2011-174 Link to ES Tech. Rep. Archives: CPM2011-174

Conference Information
Committee CPM EE  
Conference Date 2012-02-10 - 2012-02-10 
Place (in Japanese) (See Japanese page) 
Place (in English) Kikai-Shinko-Kaikan Bldg 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Battery technology, etc 
Paper Information
Registration To CPM 
Conference Code 2012-02-CPM-EE 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Effect of Zinc Surface Modification on Electrochemical Properties for Alkaline Zn-based Secondary Battery 
Sub Title (in English)  
Keyword(1) zinc/air secondary battery  
Keyword(2) anode  
Keyword(3) cation exchage polymer  
Keyword(4) cycle life  
Keyword(5) shape change  
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1st Author's Name Tomokazu Yamane  
1st Author's Affiliation Kyoto University (Kyoto Univ.)
2nd Author's Name Akiyoshi Nakata  
2nd Author's Affiliation Kyoto University (Kyoto Univ.)
3rd Author's Name Toshiro Hirai  
3rd Author's Affiliation Kyoto University (Kyoto Univ.)
4th Author's Name Zempachi Ogumi  
4th Author's Affiliation Kyoto University (Kyoto Univ.)
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Speaker Author-1 
Date Time 2012-02-10 15:35:00 
Presentation Time 25 minutes 
Registration for CPM 
Paper # EE2011-58, CPM2011-174 
Volume (vol) vol.111 
Number (no) no.433(EE), no.434(CPM) 
Page pp.33-37 
#Pages
Date of Issue 2012-02-03 (EE, CPM) 


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