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Paper Abstract and Keywords
Presentation 2008-10-10 16:15
Study on Compositional Transition Layers at Gate Dielectrics/Si Interface by using Angle-resolved X-ray Photoelectron Spectroscopy
Tomoyuki Suwa (Tohoku Univ.), Takashi Aratani (Shin-Etsu Chemi.), Masaaki Higuchi (Toshiba), Shigetoshi Sugawa (Tohoku Univ.), Eiji Ikenaga (JASRI), Jiro Ushio (Hitachi), Hiroshi Nohira (Musashi Inst. of Tech.), Akinobu Teramoto, Tadahiro Ohmi, Takeo Hattori (Tohoku Univ.) SDM2008-167 Link to ES Tech. Rep. Archives: SDM2008-167
Abstract (in Japanese) (See Japanese page) 
(in English) Soft x-ray-excited angle-resolved photoemission results for nitride films formed using nitrogen-hydrogen radicals on Si(100), Si(111), and Si(110) are reported. The data were obtained using synchrotron radiation which allowed the Si 2p, N 1s, and O 1s levels to be investigated with the same probing depth. The following main results were obtained: 1) The $Si_3$$N_4$ film is covered with one monolayer of Si-$(OH)_3$N. Its areal density is 15% smaller on Si(111) than on Si(100) and Si (110), 2) the $Si_3$$N_4$/Si interfaces on all three surfaces are compositionally abrupt. This conclusion is based on the observation that no Si atoms bonded with three N atoms and one Si atom were detected, 3) The observation that the number of Si-H bonds at the $Si_3$$N_4$/Si(110) interface is 38~53% larger than those at the $Si_3$$N_4$/Si(100) and $Si_3$$N_4$/Si(111) interfaces indicates a dependence of the interface structure on the orientation of the substrate.
Keyword (in Japanese) (See Japanese page) 
(in English) Silicon nitride film / nitrogen-hydrogen radical / Soft x-ray-excited angle-resolved photoemission / / / / /  
Reference Info. IEICE Tech. Rep., vol. 108, no. 236, SDM2008-167, pp. 69-74, Oct. 2008.
Paper # SDM2008-167 
Date of Issue 2008-10-02 (SDM) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
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Conference Information
Committee SDM  
Conference Date 2008-10-09 - 2008-10-10 
Place (in Japanese) (See Japanese page) 
Place (in English) Tohoku Univ. 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Process Science and Novel Process Technologies 
Paper Information
Registration To SDM 
Conference Code 2008-10-SDM 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Study on Compositional Transition Layers at Gate Dielectrics/Si Interface by using Angle-resolved X-ray Photoelectron Spectroscopy 
Sub Title (in English)  
Keyword(1) Silicon nitride film  
Keyword(2) nitrogen-hydrogen radical  
Keyword(3) Soft x-ray-excited angle-resolved photoemission  
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1st Author's Name Tomoyuki Suwa  
1st Author's Affiliation Tohoku University (Tohoku Univ.)
2nd Author's Name Takashi Aratani  
2nd Author's Affiliation Shin-Etsu Chemical Co., Ltd. (Shin-Etsu Chemi.)
3rd Author's Name Masaaki Higuchi  
3rd Author's Affiliation Toshiba (Toshiba)
4th Author's Name Shigetoshi Sugawa  
4th Author's Affiliation Tohoku University (Tohoku Univ.)
5th Author's Name Eiji Ikenaga  
5th Author's Affiliation JASRI (JASRI)
6th Author's Name Jiro Ushio  
6th Author's Affiliation Advanced Research Laboratory, Hitachi Ltd. (Hitachi)
7th Author's Name Hiroshi Nohira  
7th Author's Affiliation Musashi Institute of Technology (Musashi Inst. of Tech.)
8th Author's Name Akinobu Teramoto  
8th Author's Affiliation Tohoku University (Tohoku Univ.)
9th Author's Name Tadahiro Ohmi  
9th Author's Affiliation Tohoku University (Tohoku Univ.)
10th Author's Name Takeo Hattori  
10th Author's Affiliation Tohoku University (Tohoku Univ.)
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Speaker Author-1 
Date Time 2008-10-10 16:15:00 
Presentation Time 30 minutes 
Registration for SDM 
Paper # SDM2008-167 
Volume (vol) vol.108 
Number (no) no.236 
Page pp.69-74 
#Pages
Date of Issue 2008-10-02 (SDM) 


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